Bonding carbon-carbon composites through a reactant layer

ABSTRACT

An apparatus for bonding a first carbon composite to a second carbon composite through a reactant layer includes a housing, and a pair of conductive press plates electrically isolated from the housing. The press plates are adapted to position the two parts to be bonded with a reactant layer therebetween. The press plates are subjected to an electrical potential and a clamping force, sufficient to initiate a combustion reaction that creates a molten ceramic to bond together the carbon-carbon composites.

This application is a divisional of co-pending U.S. patent applicationSer. No. 11/392,341, filed Mar. 29, 2006, which published as U.S. PatentApplication Publication No. 2007/0235123 on Oct. 11, 2007. Thisapplication may be found related to U.S. Pat. No. 7,858,187, whichissued on Dec. 28, 2010. The entire content of both these applicationsis incorporated herein by reference.

TECHNICAL FIELD

This disclosure relates generally to the manufacturing of carbon-carboncomposites, such as carbon brake discs.

BACKGROUND

Carbon-carbon brake discs are widely used on commercial and militaryaircraft. Wide-bodied commercial jets required improved brake materialsbecause traditional steel brake systems simply could not absorb all ofthe thermal energy created during stops associated with landings.Carbon-based composites were developed which provide heat capacity,thermal conductivity, and thermal strength able to meet the demandingconditions involved in landing large commercial jets. On the militaryside, the lower weights as well as the thermal and strength propertiesof the carbon composites has helped to ensure their acceptance in brakeapplications.

The use of carbon-carbon composite brake discs in aircraft brakes, whichhave been referred to as carbon brakes, is well known in the aerospaceindustry. Carbon-carbon composite brake discs are manufactured byaircraft wheel and brake manufacturers using a variety of manufacturingmethods, which generally require lengthy fabrication and densificationmethods. In recent years, aircraft manufacturers have increasinglyspecified the use of such carbon-carbon composite brake discs for brakesdesigned for use with new aircraft models. In some instances, forexample in the reuse of worn carbon-carbon composite discs, it isdesirable to combine or attach two or more carbon-carbon frictionmaterials together. Typically, this is accomplished through mechanicalfasteners, such as, for example, through the use of rivets.

In at least one instance, the carbon-carbon composites are alternativelyheld together through the use of a spot-applied molten braze materialsuch as a Zirconium metal. To accomplish this, the carbon composites aresubjected to an electrical current such that the resistance in thecarbon material causes a temperature increase. A thin layer of brazematerial, such as a thin metal foil, is melted in the general area ofthe applied current. The metal melts, and after removal from theelectrical current, solidifies again to locally bond the carbon-carboncomposites. The finished brazed material, however, is subject to failureat a relatively low temperature, as the metal material need only melt torelease the bond. Additionally, the composites are subject to oxidation,as the metal utilized is typically very reactive.

Accordingly, it may be desirable to provide an apparatus capable ofbonding carbon-based composites without the need for mechanicalfasteners, and without use of a molten metal material.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 is a front perspective view of an example apparatus for bondingcarbon-based composites through a reactant layer.

FIG. 2 is a front elevational view of the example apparatus of FIG. 1.

FIG. 3 is a plan view of the example apparatus of FIG. 1.

FIG. 4 is a cross-sectional view of a press die assembly of theapparatus of FIG. 1, taken along the line 4-4 of FIG. 3.

FIG. 5 is a cross-sectional view of the press die assembly of theapparatus of FIG. 1, taken along the line 5-5 of FIG. 3.

FIG. 6 is a schematic drawing of an exemplary air/hydraulic circuit usedin conjunction with the example apparatus of FIG. 1.

FIG. 7 is a flowchart of an exemplary method of bonding carbon-basedcomposites through a reactant layer utilizing the apparatus of FIG. 1.

DETAILED DESCRIPTION

The following description of the disclosed embodiment is not intended tolimit the scope of the invention to the precise form or forms detailedherein. Instead the following description is intended to be illustrativeof the principles of the invention so that others may follow itsteachings.

Referring now to the drawings, FIG. 1 is an illustration of an exampleapparatus, such as a press 10, for bonding two carbon-based composites.The exemplary press 10 includes a housing 12, which in this embodimentgenerally includes a support frame 13, a press die assembly 14, aclamping device 16, and a protective guard 24. Additionally, the press10 may include a controller 20, and a power supply 22. While thestructure of the press 10 will be described, for ease of understanding,in conjunction with a plurality of separate components, it will beunderstood by one of ordinary skill in the art that the components maybe combined or separated in various combinations.

In this example, a lower portion 26 of the support frame 13 may includea plurality of heavy square tube frame segments 30 forming a generallyrectangular support structure. The support frame 13 may be mounted on orotherwise coupled to a suitable transportation device such as, forexample, a plurality of lockable casters 32 which may have step-on pads(not shown) to selectively hold the casters 32 stationary as desired. Anupper portion 36 of the support structure 13 may include a top plate 40,which in this example is horizontally supported by the lower portion 26of the support frame 13. Coupled to the top plate 40 is supportstructure, such as, for example, a plurality of vertically extendingheavy square tube frame segments 42. In this example, the frame segments42 support a plurality of transverse support beams 46, to form a topcrown weldment 43 adapted to support the press die assembly 14, oneexample of which is disclosed in further detail below. Optionally, thesupport frame 13 may be at least partially surrounded by the protectiveguard 24, which in this embodiment surrounds the upper portion 36 of thesupport structure 13 and is constructed of a durable material, such as,for example a plurality of shatter resistant MAKROLON® (polyacrylic)panels.

Referring to FIGS. 2 and 3, the weldment 43 may include a plurality ofrails 50, which may assist in the loading and unloading of the press dieassembly 14 by slidably receiving the press die assembly 14. Forexample, the rails 50 may include a pair of U-shaped channel rails 52,each having at least one lip extension 54 adapted to receive acorresponding top edge of the die assembly 14. To further assist in theloading and unloading of the press die assembly 14, a plurality ofcorresponding rails 56 are mounted opposite the rails 50. In thisexample, the rails 56 include a pair of L-shaped rails, each having atleast one sliding surface 62 and at least one guiding surface 64. Inother words, the press die assembly 14 is shiftable between an unloadedposition, for example, a position wherein the press die assembly 14 maybe removed or otherwise disassembled, and a loaded position, forexample, an operative position wherein the press die assembly 14 isready for processing. A limit switch (not shown) may be utilized toensure the press die assembly 14 is properly seated in the operating orloaded position. It will be appreciated by one of ordinary skill in theart that the rails 50 and 60 may be any device suitable for shifting thedie assembly 14 between the loaded and unloaded positions, such as forinstance, rollers, ball bearings, or any other suitable device.

FIGS. 4 and 5 illustrate the press die assembly 14 in the loaded oroperable position. As shown, the press die assembly 14 includes a firstdie base 70 and a second die base 72. In this example, the first diebase 70 is adapted to be slidably coupled to the channel rails 52 (seeFIG. 2). Similarly, the second die base 72 is adapted to slidably coupleto the rails 56. Mounted to each of the first and second die bases 70,72, respectively, is a first conductive press plate 74 and a secondconductive press plate 78, each of which may be, for example, formedfrom a copper alloy. As illustrated, each of the press plates 74, 78 iselectrically isolated from its corresponding die base 70, 72, andaccordingly, from the housing 12. For example, to electrically isolatethe press plates 74, 78, from the die bases 70, 72, the press plates 74,78 may be mounted to the die bases 70, 72 with at least one high currentpower supply insulator 80, such as, for example, an electrical gradepolytetrafluoroethylene (PTFE). Additionally, to further assist in theelectrical isolation of the press plates 74, 78, a dielectric material82, such as, for example zirconium phosphate, may be mounted between thedie bases 70, 72 and the press plates 74, 78. It will be appreciatedthat in the illustrated example, the dielectric material 82 may be anysuitable dielectric, including, for example, zirconium phosphate asdisclosed.

Each press plate 74, 78 is electrically coupled to the power supply 22such that the power supply 22 creates an electric potential across theplates 74, 78, and therefore the carbon composite parts. In thisexample, each press plate includes at least one aperture 84 to securelycouple the plate with the power supply 22 through suitable flexiblewiring (not shown). In one embodiment, the power supply 22 provides ahigh voltage, direct current (DC), but it will be appreciated that anysuitable power supply may be utilized, including alternating circuit(AC).

To bond at least two carbon-based composites, such as, for example,carbon-carbon composites, the press plates 74, 78 are adapted to hold amold, such as a carbon-carbon assembly 85 therebetween. For instance, inoperation, the two press plates 74, 78 are adapted to support thecarbon-carbon assembly 85 including a first carbon-carbon composite disc86 and a second carbon-carbon composite disc 88, such as, for examplecarbon discs suitable for use in an aircraft braking mechanism. Thediscs 86, 88 have a reactant layer 90 placed between the two discs on atleast a portion of the surface of the discs 86, 88 intended to bebonded. The reactant layer 90 may be any suitable bonding layer, suchas, for instance, a carbide forming metal optionally mixed with carbonpowder such as titanium and carbon. Additionally, to assist in heatretention, the carbon-carbon assembly 85 may optionally include athermal insulator 92 surrounding at least a portion of the carbon-carbonassembly 85. Still further, at least a portion of the carbon-carbonassembly 85 may optionally be enclosed in a retaining band 94 which inthis illustration surrounds at least a portion of the thermal insulator92, but may alternatively surround at least a portion of the discs 86,88, or the reactant layer 90. The retaining band 94 may provideadditional support and safety due to the elevated amount of heat andpressure required to initiate the combustion synthesis of the two discs88, 90. A thermocouple (not shown) may be optionally placed proximatethe reactant layer 90 to monitor the temperature during any part of themanufacturing cycle. For example, the thermocouple (not shown) may beoperatively coupled near the reactant layer 90 by being imbedded in theretaining band 94 and/or the thermal insulator 92, or may be located atany suitable location so that the temperature of the area proximate thereactant layer 90 may be monitored, analyzed, and/or otherwise recorded.Additionally, the thermocouple may be operatively coupled to thecontroller 20, wherein the temperature may be further analyzed and/orprocessed.

Turning now to FIG. 6, there is illustrated an exemplary clamping device16. The clamping device 16 may be any suitable assembly capable ofproviding a controlled force to the press die assembly 14. In thisexample, the clamping device 16 is an air and hydraulic circuit 100,capable of providing a powerful, controlled, and fast acting pressforce. As shown, the circuit 100 includes a work cylinder 102 having awork portion 102 a, an exhaust portion 102 b and a drive portion 102 c.As best illustrated in FIG. 2, the drive portion 102 c engages a halfcollar 104 at the bottom of the press die assembly 14 to operativelycouple the circuit 100 with the press die assembly 14.

Returning to FIG. 6, the work portion 102 a of the work cylinder 102 iscoupled through a hydraulic valve 104 to a lower chamber 106 a of ahydraulic booster 106, as well as an oil portion of an air/oil tank 108.The hydraulic booster 106 includes a lower chamber 106 a, a middlechamber 106 b, and an upper chamber 106 c. In this embodiment, thehydraulic booster 106 provides approximately a 25.3:1 pressure ratio,and accordingly, a corresponding 100 lbs/in² pressure input maycorrespond to a pressure output of 2,530 lbs/in². The hydraulic valve104 includes a solenoid 105 that in operation releases to quickly allowpressure built into the hydraulic booster 106 to be delivered to thework cylinder 102, thereby quickly driving the drive portion 102 c ofthe work cylinder 102 upward to quickly provide the press die assembly14 with a precise force. Monitoring the pressure in the lower chamber106 a of the hydraulic booster 106 is a pressure transducer 109. Thepressure transducer 109 is operatively coupled to the hydraulic valve105 to ensure the solenoid 105 does not release until the pressure inthe system has achieved the proper desired setting.

The exhaust portion 102 b of the work cylinder 102 is coupled to themiddle chamber 106 b of the hydraulic booster 106, as well as to an airvalve 110. The air valve 110 includes a muffler 112 and an air filterregulator 114 having an air supply 116, a gauge 117, and a drain 118.The air valve 110 is coupled to an air portion of the air/oil tank 108through a flow control device 120. The flow control device 120 includesan adjustable orifice 122 and a check valve or ball funnel 124. Theadjustable orifice 122 controls the flow rate through the flow controldevice 120 in one direction, while the ball funnel 124 allows air totravel through the ball funnel in only one direction. Thus, inoperation, the flow control device 120 forces air through the orifice122 in one direction while allowing air to flow through both the orifice122 and the ball funnel 124 in an opposite direction.

The pressure in the air/hydraulic circuit 100 is controlled by aproportional air valve 126. The proportional air valve 126 includes afilter regulator 128 having an air supply 130 and a drain 132. Theproportional air valve 126 is coupled to the upper chamber 106 c of theair hydraulic booster 106 through a ball funnel 134 located in a quickexhaust valve 136. The quick exhaust valve 136 may be utilized toquickly release the pressure within the circuit 100. To initiate apressure in the circuit 100, the proportional air valve 126 receives avoltage (e.g., a control signal from the controller 20) and supplies acorresponding pressure to the upper chamber 106 c. For example, theproportional air valve 126 may receive a voltage ranging from 0 to 10volts, and output a corresponding 0 to 100 lbs/in². As described above,through the air hydraulic booster 106, the input pressure may be boostedat a 25.3:1 ratio, and therefore, a 5 volt input to the proportional airvalve 126 may result in a 1,265 lbs/in² output pressure by the hydraulicbooster 106 to the work cylinder 102. In this manner, the compressionforce utilized during the combustion synthesis bonding may be preciselydelivered to the press die assembly 14.

FIG. 7 illustrates a flowchart of one exemplary method of combustionsynthesizing two carbon-based composites utilizing the press 10 andgenerally referred to by reference numeral 200. In particular, the press10 may be utilized to bond at least two carbon-carbon composite frictionmaterials by the initiation of combustion synthesis within a reactantlayer. In this exemplary method 200, the press 10 is prepared for usageby the placement of at least the two carbon-carbon composite discs 86,88 between the press plates 74, 78 of the press dies assembly 14 (block202). A reactant layer 90 is placed between at least a portion of thesurfaces of the discs 86, 88 to be bonded. In this example of thepreparation of the press die assembly 14, the press 10 is moved to theunloaded position and is prepared with the first carbon-carbon compositedisc 86 and the second carbon-carbon composite disc 88. As part of thepreparation (block 202), the reactant layer 90, such as for instance,titanium and optionally carbon powder is placed between the two discs86, 88. As disclosed above, the discs 86, 88 may be optionally wrappedin the thermal insulator 92, and still further may be optionally held bythe retaining band 94. Additionally, a thermocouple may be positionedproximate the reactant layer 90 and operatively coupled to thecontroller 20 to monitor the temperature during the combustion synthesisprocess.

Once the assembly 14 is prepared, it is moved to the loaded position,where it is ready for processing (block 204). As noted previously, alimit switch, or other suitable detection device may be utilized toensure the press die assembly 14 is properly seated in the operatingposition. Further, a safety switch (not shown) may be utilized to verifythe proper closing of the protective guard 24 if such a guard isinstalled. At any time prior to or during the initiation of thecombustion synthesis process, the controller 20 may be programmed forthe execution of a desired manufacturing sequence. For example, thecontroller 20 may be programmed with a desired energy level forcombustion synthesis (block 206) (e.g., a maximum current to correspondto a desired created temperature), a desired initial holding force(block 208), and a maximum desired loading force (block 210), including,for example, a delay time before the application of the loading forceand the time of application of maximum loading force. It will beappreciated by one of ordinary skill in the art that the controller 20may be any suitable programmable device, including for example, aprogrammable logic controller (PLC), a personal computer, or othersuitable controller. In one example utilizing titanium and carbon powderas the reactant layer, the controller 20 may be programmed with aninitial loading force of 500 lbs/in², a maximum loading force of 7400lbs/in², a delay time of maximum force application of 1 second, a timeof maximum force application of 10 seconds, a maximum current of 600Amps, a time of current of 5 seconds, and an initial temperature of 30°C.

After the controller 20 is programmed, and the press die assembly 14properly loaded, the combustion synthesis reaction may be initialized asprogrammed (block 212). In particular, the programmed holding force isapplied to the press die assembly 14 and the proper pressure in theclamping device 16 is developed such that the work cylinder 102 canimpart the programmed maximum force to the press die assembly 14. Oncethe proper pressure is developed, the power supply 22 and the workcylinder 102 are activated, and the combustion synthesis process isinitiated and completed. For example, the electric potential developedacross the plates 74, 78, and accordingly across the carbon discs 86, 88and the reactant layer 90, is released to initiate a combustion reactionthat creates a molten ceramic that in turn bonds the carbon-carboncomposite discs 86, 88 with ceramic. In one example, utilizing theparameters noted above, the entire process may take approximately 10seconds to complete. It will be appreciated by one of ordinary skill inthe art that the order of execution of the combustion synthesis stepsmay be changed, and/or some of the steps described may be changed,eliminated, combined and/or subdivided into multiple steps. Finally,after the combustion synthesis reaction is completed, the press dieassembly 14 may be shifted to the unloaded position (block 214) and thebonded material (i.e., the discs 86, 88) may be removed (block 216).

Although the teachings of the invention have been illustrated inconnection with certain embodiments, there is no intent to limit theinvention to such embodiments. On the contrary, the intention of thisapplication is to cover all modifications and embodiments fairly fallingwithin the scope of the appended claims either literally or under thedoctrine of equivalents. Further, although the example processes aredescribed with reference to the flowchart illustrated in FIG. 7, personsof ordinary skill in the art will readily appreciate that many othertechniques for implementing the example methods and apparatus describedherein may alternatively be used. For example, with reference to theflowchart illustrated in FIG. 7, the order of execution of the blocksmay be changed, and/or some of the blocks described may be changed,eliminated, combined and/or subdivided into multiple blocks.

1. A system comprising: a first carbon composite; a second carboncomposite; a reactant layer; a housing; a first conductive press platecoupled to the housing and being electrically insulated therefrom andadapted to position the first carbon composite; a second conductivepress plate supported by the housing opposite the first conductive pressplate and being electrically insulated from the housing, wherein atleast one of the first and second conductive press plates aretranslatable toward the opposite press plate, the first and second pressplates further being adapted to align the first and second carboncomposites therebetween, with the reactant layer being between at leasta portion of surfaces of the first and second carbon composites to bebonded together; a clamping device operatively coupled to at least oneof the first and second conductive press plates, wherein the clampingdevice is configured to transmit a force to the first and secondconductive press plates to compress the first and second carboncomposites and the reactant layer between the press plates; and a powersupply operatively coupled to the first and second conductive pressplates and configured to create an electric potential across the firstand second conductive press plates while the first and second conductivepress plates compress the first and second carbon composites, whereinthe electric potential increases a temperature of the reactant layer. 2.The system of claim 1, further comprising a dielectric materialinterposed between at least one of the first or second conductive pressplates and the housing to assist in electrically isolating the at leastone of the first or second conductive press plates from the housing. 3.The system of claim 1, wherein the first and second press plates areremovable from the clamping device.
 4. The system of claim 1, furthercomprising a thermal insulator surrounding at least a portion of anouter surface of at least one of the reactant layer or the first andsecond carbon composites.
 5. The system of claim 1, further comprising aretaining band surrounding at least a portion of an outer surface of atleast one of the reactant layer or the first and second carboncomposites.
 6. The system of claim 1, further comprising a thermocouplelocated proximate the reactant layer and configured to monitor thetemperature of the reactant layer.
 7. The system of claim 1, furthercomprising a protective guard surrounding at least a portion of thehousing.
 8. The system of claim 1, further comprising a controllerconfigured to: control the clamping device to press the first and secondcarbon composites together under a force, with the reactant layertherebetween; and control the power supply to create an electricpotential across the reactant layer to initiate a combustion reactionand create a molten ceramic thereby bonding the first and second carboncomposites together.
 9. The system of claim 8, wherein the controllercomprises a programmable logic controller.
 10. The system of claim 1,wherein the clamping device comprises a hydraulic cylinder.
 11. Thesystem of claim 10, wherein the hydraulic cylinder is operated by atleast one of an air circuit comprising a hydraulic booster or ahydraulic circuit comprising a hydraulic booster.
 12. The system ofclaim 10, wherein the hydraulic cylinder is operatively coupled to asolenoid.
 13. The system of claim 1, wherein the reactant layercomprises a ceramic.
 14. The system of claim 1, wherein at least one ofthe first or second carbon composites comprises a carbon brake discpart.
 15. The system of claim 1, wherein the electric field isconfigured to increase the temperature of the reactant layer above atemperature required to initiate a combustion synthesis reaction. 16.The system of claim 1, wherein the reactant layer comprises titanium andcarbon powder.
 17. The system of claim 1, wherein the clamping device isconfigured to press the reactant layer and the first and second carboncomposites together under a force of 1265 lbs/in² to 2530 lbs/in². 18.The system of claim 1, further comprising a first die base and a seconddie base, wherein the first conductive press plate is mounted to thefirst die base and the second conductive press plate is mounted to thesecond die base, the system further comprising a dielectric materialpositioned between the first conductive press plate and the first diebase and between the second conductive press plate and the second diebase.
 19. The system of claim 1, wherein the first and second conductivepress plates are each electrically insulated from the housing by a highcurrent power supply insulator.
 20. The system of claim 19, wherein thehigh current power supply insulator comprises polytetrafluoroethylene.